is there a special programable thermostat for 4 zone boiler heat system

Short answer, no. If you give a little more detail, we can offer you some ideas.
Basically, you have 4 zones, in 4 locations, therefore you need 4 thermostats.
Most programmable thermostats could/should work, but keep in mind usually with programmable thermostats, the user typically wants to employ setbacks, which depending on your system and your emitters might not be a good idea to employ deep setbacks.

This might work for you if your piping is set up right http://www.ivar-group.com/LR_DMS_ECommerce_Portlet-portlet/enhancedDownloadEngine/IVAR/Document/COVER/306600/Equicalor US.pdf?time=1416086858314

Harvey