Blue corrosion on all copper press-fit coupling fittings

marius888

SuperTech said:

marius888 said:

EBEBRATT-Ed said:

@marius888

is this part of your heating system? Do you know if this system contains antifreeze

Yes, from what I'm observing only the heating system is affected.
I'm not sure if the system contains antifreeze or not, I'm planning to test what is inside, already in discussion with the guys from rhomarwater to see what they need.
I'm starting to think that I should replace the whole heating system + pipes, I have 4 zones (two hydro, one baseboard and one indirect water heater ).

Two hydro air units....is one in the attic? I would bet it is. If so then I would bet your system has glycol antifreeze in it and that is the root of your problem.  The glycol is probably old and needs replacing anyway, I'd dump it and repair all leaks with soldered joints.

After some serious detective work I was able to trace the company that installed the system and yes has glycol antifreeze.
The owner is saying it was service yearly and they did the proper maintenance. but I'm suspecting he is just lying

JUGHNE

There are many definitions of "proper maintenance".
Somewhere between 20 minutes or 3 hours.
Most homeowners don't know that they don't know.

HomerJSmith

2004, well that pretty much kills the glycol. The pro fit was probably a repair or addition after the initial installation. I believe in testing. I get into trouble when I assume that what the customer is telling me is what IS. Trust, but verify! You can assume the glycol is still OK, but for how long? I recommend fixing leaks, draining, flushing, and a new glycol fill if needed.

Derheatmeister

"hot_rod" said:

Richard, most oil change shops will take small quantities of glycol, 5 gallon buckets. Pretty much any dealer or repair shop has glycol recycling same with O Reilly auto parts, etc.
They do mix EG and PG in the recycling drums, it's tough to know which is in vehicles these days.
Safety Kleen takes large quantities, drums, but for a fee.

Most airports recycle the glycol de-icers. It goes into a bio pond for a few days for O2 exposure then into the sewer system if it is not recycled.

Actually EG breaks down quicker than PG and used to be used for deicers. Info I learned from the Dow engineers that did a seminar for Coffee with Caleffi.



Thanks for the infomation regarding the recycling at O Reilly's..Did not know that !
We collect it in 55 Gallon drums,Low E in Denver picks it up and takes it down to Chemical Specialties for refinement.
Most plumbers around here just dump it down the drain..
In Europe this is highly illegal for various reasons.

1. Any Heavy Metal that is entrained is hard to remove by the sewer treatment plants.
Dumping glycol is no different than what the mining industrie used to do in the 1800.
Here in Colorado we still have rivers that are affected by these practices

2. Some Glycols have Phosphorus properties which is very bad for the enviroment/Aquatic life.

3. They Rather punch the Wine with it versus putting it down the Drain....

mattmia2

I always wondered what was in four loko.

EBEBRATT-Ed

Some of those fittings are probably past saving but if it was my own house I would clean up the ones that aren't too bad and braze them like refrigeration fittings.

mattmia2

that could get interesting with the o-rings

pecmsg

mattmia2 said:

that could get interesting with the o-rings

It’s doable. The O-Rings burn away. You would have to clean them up really well. 

Derheatmeister

pecmsg said:

mattmia2 said:

that could get interesting with the o-rings

It’s doable. The O-Rings burn away. You would have to clean them up really well. 



We should make a video of someone trying to Braze a Pro press joint....Ha

hot_rod

HomerJSmith said:

2004, well that pretty much kills the glycol. The pro fit was probably a repair or addition after the initial installation. I believe in testing. I get into trouble when I assume that what the customer is telling me is what IS. Trust, but verify! You can assume the glycol is still OK, but for how long? I recommend fixing leaks, draining, flushing, and a new glycol fill if needed.

depending on the quality of the original glycol and how it was installed, glycol can last 20 years. Dirty systems, hard mix water, Oxygen ingress, and constant over-heating tend to break down the inhibitors. The Ph is the indicator, and Rhomar can determine that.

Regardless of bad glycol, low Ph, it should not seep around that many joints. EPDM o-rings can handle glycolic acid, which is what you get when glycol inhibitors break down.

The crimp connection on some air vents and threaded fittings also experience this fuzz, sometimes. It's a tough fluid to work with. Hard to purge air out of also.

Makes one wonder if the stains appear outside the joint does O2 get into the system, like a non-barrier tube? It's that "molecular" level term that concerns me:0
Be a bummer if some O-ring seal fittings are allowing O2 into hydronics.

hot_rod

Derheatmeister said:

"hot_rod" said:

Richard, most oil change shops will take small quantities of glycol, 5 gallon buckets. Pretty much any dealer or repair shop has glycol recycling same with O Reilly auto parts, etc.
They do mix EG and PG in the recycling drums, it's tough to know which is in vehicles these days.
Safety Kleen takes large quantities, drums, but for a fee.

Most airports recycle the glycol de-icers. It goes into a bio pond for a few days for O2 exposure then into the sewer system if it is not recycled.

Actually EG breaks down quicker than PG and used to be used for deicers. Info I learned from the Dow engineers that did a seminar for Coffee with Caleffi."

Thanks for the infomation regarding the recycling at O Reilly's..Did not know that !
We collect it in 55 Gallon drums,Low E in Denver picks it up and takes it down to Chemical Specialties for refinement.
Most plumbers around here just dump it down the drain..
In Europe this is highly illegal for various reasons.

1. Any Heavy Metal that is entrained is hard to remove by the sewer treatment plants.
Dumping glycol is no different than what the mining industrie used to do in the 1800.
Here in Colorado we still have rivers that are affected by these practices

2. Some Glycols have Phosphorus properties which is very bad for the enviroment/Aquatic life.

3. They Rather punch the Wine with it versus putting it down the Drain....

Always best to recycle. I visited a glycol recycler in Missouri. they filter, then RO old glycol. Add inhibitor packages depending on the use, and re-color it.

The glycol that is recycled is a blend of EG and PG, since cars use both types now. So I would not use recycled glycol if it could come in contact with potable water.

Hydronic glycol should start with new glycol, corn based glycol if you are a true purist.
The solar glycol Caleffi sold was plant based.

Hard to say no to antifreeze with a shredder as the spokes-model