Steam boiler with a hydronic circuit

Darin

Going back to the steam boiler that provides heat to a hydronic circuit, is there a way to insure that the hydronic circuit maintains its "charge" and doesn't loose its prime over the off season or when the water line goes below the inlet to the hydronic circuit(the return is tapped into the wet return). Do the flow control valves insure a air less hydronic circuit and a reliable start up in the fall?