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Want to insulate walls with heat risers

Hi, My office has heat risers inside the corner walls that provide heat to upper floors so my office is sweltering. Opening windows gets me cold air and a sinus infection. Air conditioning and humidifiers don't help I want to insulate the wall where the riser is with something like an insulated wallpaper that won't catch fire. One wall is about 28 in X 14 feet and the adjoining is about 14in X 14ft.Does such a thing exist? Thank you.