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Radiator NOT returning Condensate to Boiler.

Hey Y'all
One pipe steam system, has a vaporstat set at 10/4. This is a two family house and this system heats the 2nd and 3rd floors. All of the Rads get hot but the one of 2 on the same steam riser to the 3rd floor is holding it's condensate enough so that when it gets to a certain point is starts to leak out the radiator. Radiator is pitched properly and radiator valve is working properly (fully open, nothing broken inside of it. When I take off the vent you hear an audible vacuum release sound allowing air in and then the condensate returns to the boiler. Changing the vent hasn't helped it was a # 40 Hoffman to a Hoffman 1A. The steam riser originally fed the radiators to the 3rd floor was changed from the first floor to the 2nd floor steam main and goes up a chase from the basement to the 3rd floor to feed this radiator and another one also no issues with that radiator. been an ongoing problem and looking for an answer to this issue so I can get this dang house off of my service list.
One pipe steam system, has a vaporstat set at 10/4. This is a two family house and this system heats the 2nd and 3rd floors. All of the Rads get hot but the one of 2 on the same steam riser to the 3rd floor is holding it's condensate enough so that when it gets to a certain point is starts to leak out the radiator. Radiator is pitched properly and radiator valve is working properly (fully open, nothing broken inside of it. When I take off the vent you hear an audible vacuum release sound allowing air in and then the condensate returns to the boiler. Changing the vent hasn't helped it was a # 40 Hoffman to a Hoffman 1A. The steam riser originally fed the radiators to the 3rd floor was changed from the first floor to the 2nd floor steam main and goes up a chase from the basement to the 3rd floor to feed this radiator and another one also no issues with that radiator. been an ongoing problem and looking for an answer to this issue so I can get this dang house off of my service list.
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Comments
Could there be some Hoffman 76's (vacuum vents) on the mains?
can you see how much vacuum there is in the system on the gauge?--NBC