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Plug for HW air vent?

Refinishing an old wall rad that had at one time been used as a HW rad- I'll be using it with one pipe steam. I'm going to have them powdercoated and want to plug the 1/4" tap where the old air vent went (and I'll have to tap a new one for the steam vent). Is a brass plug appropriate here, or will I have issues with expansion/contraction?
Thanks,
Patrick

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